• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    A refrigerant circuit (2) includes a first flow path (C1) through which a downstream side of a first evaporator (11) and an upstream side of a low-stage side compressor (3) are connected to each other, a first valve (21) which opens or closes the first flow path (C1), a second flow path (C2) through which the downstream side of the first evaporator (11) and an upstream side of a high-stage side compressor (4) are connected to each other, a second valve (22) which opens or closes the second flow path (C2), a third flow path (C3) through which a downstream side of a second evaporator (12) and the upstream side of the low-stage side compressor (3) are connected to each other, a third valve (23) which opens or closes the third flow path (C3), a fourth flow path (C4) through which the downstream side of the second evaporator (12) and the upstream side of the high-stage side compressor (4) are connected to each other, and a fourth valve (24) which opens or closes the fourth flow path (C4).
    公开号:EP3708924A1
    申请号:EP18877202.4
    申请日:2018-11-08
    公开日:2020-09-16
    发明作者:Takayuki Kobayashi；Yohei Katsurayama；Hiroshi Nakayama；Yasuharu TOKUNAGA
    申请人:Kansai Electric Power Co Inc；Chubu Electric Power Co Inc；Mitsubishi Heavy Industries Thermal Systems Ltd；
    IPC主号:F25B1-00
    专利说明:
    [0001] The present invention relates to a heat pump including a refrigerant circuit.
    [0002] Priority is claimed on Japanese Patent Application No. 2017-215660, filed November 8, 2017 , the content of which is incorporated herein by reference. [Background Art]
    [0003] In the related art, a refrigeration cycle including a refrigerant circuit through which a refrigerant circulates while being repeatedly compressed and expanded, that is, a heat pump is known. In this heat pump, for example, as described in Patent Document 1, a refrigerant may be compressed in two stages by a low-stage side compressor which compresses a refrigerant and a high-stage side compressor which further compresses the refrigerant discharged from the low-stage side compressor.
    [0004] Moreover, the heat pump includes an evaporator which evaporates the refrigerant on an upstream side of the low-stage side compressor. For example, the evaporator is a heat exchanger which exchanges heat between the refrigerant and a heating medium such as water or air. [Citation List][Patent Document]
    [0005] [Patent Document 1] Japanese Unexamined Patent Application, First Publication No. 2016-90102 [Summary of Invention][Technical Problem]
    [0006] Here, in a heat pump of Patent Document 1, a refrigerant from an evaporator is introduced into a low-stage side compressor, and thereafter is introduced into a high-stage side compressor.
    [0007] However, a heat exchange amount in the evaporator is not always constant, and may fluctuate due to an environmental factor or the like. Accordingly, a temperature of a refrigerant introduced from a heat exchanger into the low-stage side compressor is not constant, and the refrigerant introduced into the low-stage side compressor may not be in a state optimum for compression in the low-stage side compressor. In some cases, efficient operation of the entire heat pump cannot be performed.
    [0008] Therefore, the present invention provides a heat pump which can introduce a refrigerant in a state optimum for compression into a low-stage side compressor and a high-stage side compressor and can perform an efficient operation. [Solution to Problem]
    [0009] According to a first aspect of the present invention, there is provided a heat pump including: a low-stage side compressor; a high-stage side compressor which is connected to a downstream side of the low-stage side compressor in series, a condenser which is connected to a downstream side of the high-stage side compressor; an expansion mechanism which is connected to a downstream side of the condenser; a first evaporator and a second evaporator which are connected to a downstream side of the expansion mechanism in parallel; a first flow path through which a downstream side of the first evaporator and an upstream side of the low-stage side compressor are connected to each other; a first valve which opens or closes the first flow path; a second flow path through which the downstream side of the first evaporator and an upstream side of the high-stage side compressor are connected to each other; a second valve which opens or closes the second flow path; a third flow path through which a downstream side of the second evaporator and the upstream side of the low-stage side compressor are connected to each other; a third valve which opens or closes the third flow path; a fourth flow path through which the downstream side of the second evaporator and the upstream side of the high-stage side compressor are connected to each other; and a fourth valve which opens or closes the fourth flow path.
    [0010] Accordingly, the heat pump includes the first evaporator and the second evaporator. That is, the heat pump has a multi-source type refrigerant circuit including a plurality of heat exchangers having different heat exchange amounts or installation environments.
    [0011] Here, in each evaporator, a heat exchange amount fluctuates and a temperature of the refrigerant is changed. Accordingly, in some cases, the state of the refrigerant directed toward the low-stage side compressor and the high-stage side compressor may not be optimum for compression in the low-stage side compressor and the high-stage side compressor. Here, by opening or closing the first flow path, the second flow path, the third flow path, and the fourth flow path by the first valve, the second valve, the third valve, and the fourth valve, not only can the refrigerant be introduced from the first evaporator into the low-stage side compressor, but also the refrigerant can be directly introduced into the high-stage side compressor by bypassing the low-stage side compressor. Further, at the same time as switching of an introduction path of the refrigerant from the first evaporator to the compressor, an introduction path of the refrigerant from the second evaporator to the compressor can be switched. That is, not only can the refrigerant be introduced from the second evaporator into the low-stage side compressor, but also the refrigerant can be directly introduced into the high-stage side compressor by bypassing the low-stage side compressor.
    [0012] Therefore, it is possible to switch the introduction path of the refrigerant to a compressor capable of performing optimum compression according to the state of the refrigerant flowing out from each evaporator.
    [0013] In the heat pump according to a second aspect of the present invention, in the first aspect, the heat pump may further include a control unit which controls opening or closing operations of the first valve, the second valve, the third valve, and the fourth valve according to loads on the first evaporator and the second evaporator.
    [0014] By providing the control unit, the introduction path of the refrigerant can be automatically switched so that the refrigerant is introduced into the compressor capable of performing optimum compression according to the state of the refrigerant flowing out from each evaporator.
    [0015] In the heat pump according to a third aspect of the present invention, in the second aspect, the control unit may control the opening or closing operations of the first valve, the second valve, the third valve, and the fourth valve so that a first state where a refrigerant from the first evaporator is introduced into the low-stage side compressor and a refrigerant from the second evaporator is directly introduced into the high-stage side compressor and a second state where the refrigerant from the first evaporator is directly introduced into the high-stage side compressor and the refrigerant from the second evaporator is introduced into the low-stage side compressor are switchable to each other.
    [0016] According to this heat pump, since the flow of the refrigerant can be switched between the first state and the second state, the flow of the refrigerant from the first evaporator and the flow of the refrigerant from the second evaporator do not interfere with each other, the refrigerant circulates so that the flow of the refrigerant from the first evaporator and the flow of the refrigerant from the second evaporator cross each other, and the refrigerant can be introduced into an optimum compressor. Therefore, a degree of freedom of an operation increases, and an efficient operation can be performed. [Advantageous Effects of Invention]
    [0017] According to the above-described heat pump, the refrigerant in the state optimum for compression can be introduced into the low-stage side compressor and the high-stage side compressor, and an efficient operation can be performed. [Brief Description of Drawings]
    [0018] Fig. 1 is an overall configuration diagram of a heat pump according to an embodiment of the present invention. Fig. 2 is an overall configuration diagram of the heat pump according to the embodiment of the present invention and illustrates a case where a refrigerant circulates in an A mode. Further, a location through which the refrigerant does not flow is indicated by a broken line. Fig. 3 is an overall configuration diagram of the heat pump according to the embodiment of the present invention and illustrates a case where a refrigerant circulates in a B mode. Further, a location through which the refrigerant does not flow is indicated by a broken line. Fig. 4 is an overall configuration diagram of the heat pump according to the embodiment of the present invention and illustrates a case where a refrigerant circulates in a C mode. Further, a location through which the refrigerant does not flow is indicated by a broken line. Fig. 5 is an overall configuration diagram of the heat pump according to the embodiment of the present invention and illustrates a case where a refrigerant circulates in a D mode. Further, a location through which the refrigerant does not flow is indicated by a broken line. [Description of Embodiments]
    [0019] Hereinafter, a heat pump 1 according to the embodiment of the present invention will be described.
    [0020] As illustrated in Fig. 1, the heat pump 1 according to the present embodiment has a refrigerant circuit 2 which is operated in a two-stage compression cycle. The refrigerant circuit 2 has a low-stage side compressor 3, a high-stage side compressor 4, a condenser 5, an expansion valve (expansion mechanism) 6, and an evaporator 10, and the components are connected by a pipe 15 in this order. Then, for example, a refrigerant R such as carbon dioxide circulates through the refrigerant circuit 2. Here, the refrigerant R is not particularly limited to carbon dioxide.
    [0021] The low-stage side compressor 3 sucks the refrigerant R and compresses the refrigerant R.
    [0022] The high-stage side compressor 4 is connected in series to the low-stage side compressor 3, and compresses the refrigerant R discharged from the low-stage side compressor 3 to a higher pressure.
    [0023] The condenser 5 exchanges heat between the high-temperature and high-pressure refrigerant R discharged from the high-stage side compressor 4 and a heating medium R1 such as air or water to cool and condense the refrigerant R.
    [0024] The expansion valve 6 adiabatically expands the refrigerant R from the condenser 5 and decompresses the refrigerant R. A plurality (two in this embodiment) of expansion valves 6 are provided on an upstream side (inlet side) of the evaporator 10 in correspondence with a first evaporator 11 and a second evaporator 12 described later.
    [0025] In the present embodiment, the first evaporator 11 and the second evaporator 12 are provided as the evaporator 10. The first evaporator 11 and the second evaporator 12 are provided in parallel.
    [0026] The first evaporator 11 is an air heat exchanger which performs heat exchange between the refrigerant R which has passed through the expansion valve 6 and air serving as the heating medium R2, for example.
    [0027] The pipe 15 between the first evaporator 11 and an upstream side (suction side) of the low-stage side compressor 3 forms a first flow path C1. The first flow path C1 includes a first valve 21 which opens or closes the first flow path C1 so that the refrigerant R can flow through the first flow path C1 or cannot flow through the first flow path C1.
    [0028] The pipe 15 between the first evaporator 11 and an upstream side (a suction side of the high-stage side compressor 4 and a discharge side of the low-stage side compressor 3) of the high-stage side compressor 4 forms a second flow path C2. The second flow path C2 includes a second valve 22 which opens or closes the second flow path C2 so that the refrigerant R can flow through the second flow path C2 or cannot flow through the second flow path C2. In the present embodiment, the first flow path C1 is provided so as to branch from the second flow path C2 on an upstream side of a position where the second valve 22 is provided, that is, on a side closer to the first evaporator 11.
    [0029] The second evaporator 12 is a water heat exchanger which performs heat exchange between the refrigerant R which has passed through the expansion valve 6 and water serving as the heating medium R3, for example.
    [0030] The pipe 15 between the second evaporator 12 and the upstream side (suction side) of the low-stage side compressor 3 forms a third flow path C3. The third flow path C3 includes a third valve 23 which opens or closes the third flow path C3 so that the refrigerant R can flow through the third flow path C3 or cannot flow through the third flow path C3. In the present embodiment, the first flow path C1 is connected to the third flow path C3 on a downstream side of a position where the third valve 23 is provided, that is, at a position closer to the low-stage side compressor 3.
    [0031] The pipe 15 between the second evaporator 12 and the upstream side (the suction side of the high-stage side compressor 4 and the discharge side of the low-stage side compressor 3) of the high-stage side compressor 4 forms a fourth flow path C4. The fourth flow path C4 includes a fourth valve 24 which opens or closes the fourth flow path C4 so that the refrigerant R can flow through the fourth flow path C4 or cannot flow through the fourth flow path C4. In the present embodiment, the fourth flow path C4 is provided so as to branch from the third flow path C3 on an upstream side of a position where the third valve 23 is provided, that is, on a side closer to the second evaporator 12.
    [0032] Further, in this embodiment, a control unit 30 such as a MICRO-PROCESSING UNIT (MPU) for opening or closing the first valve 21, the second valve 22, the third valve 23, and the fourth valve 24 is provided.
    [0033] The control unit 30 opens or closes the first valve 21, the second valve 22, the third valve 23, and the fourth valve 24 according to loads (heat exchange amounts) on the first evaporator 11 and the second evaporator 12.
    [0034] Next, a control method of the opening or closing operation of each valve in the control unit 30 will be described.
    [0035] Hereinafter, a temperature of the refrigerant R flowing out from the first evaporator 11 is defined as T1, and a temperature of the refrigerant R flowing out from the second evaporator 12 is defined as T2. [A mode]
    [0036] A case where T1 <T2 is satisfied is an A mode (first state). In this mode, as illustrated in Fig. 2, the control unit 30 closes the second valve 22 and opens the first valve 21 so that the refrigerant R from the first evaporator 11 is introduced into the low-stage side compressor 3. Therefore, the refrigerant R from the first evaporator 11 is compressed by the low-stage side compressor 3, and thereafter, is compressed by the high-stage side compressor 4.
    [0037] Further, in this mode, the control unit 30 closes the third valve 23 and opens the fourth valve 24 so that the refrigerant R from the second evaporator 12 is introduced only into the high-stage side compressor 4 without passing through the low-stage side compressor 3. Therefore, the refrigerant R from the second evaporator 12 is compressed only by the high-stage side compressor 4. [B mode]
    [0038] A case where T1> T2 is a B mode (second state). In the present mode, as illustrated in Fig. 3, the control unit 30 closes the first valve 21 and open the second valve 22 so that the refrigerant R from the first evaporator 11 is introduced only into the high-stage side compressor 4 without passing through the low-stage side compressor 3. Therefore, the refrigerant R from the first evaporator 11 is compressed only by the high-stage side compressor 4 without passing through the low-stage side compressor 3.
    [0039] In addition, in this mode, the control unit 30 closes the fourth valve 24 and opens the third valve 23 so that the refrigerant R from the second evaporator 12 is introduced into the low-stage side compressor 3. Therefore, the refrigerant R from the second evaporator 12 is compressed by the low-stage side compressor 3, and thereafter, is compressed by the high-stage side compressor 4. [C mode]
    [0040] A C mode is when T1 ≒ T2 is satisfied and the temperature of the refrigerant R flowing out from the condenser 5 is equal to T1 and T2. In this mode, as illustrated in Fig 4, the control unit 30 stops an operation of the low-stage side compressor 3. Further, the control unit 30 closes the first valve 21 and the third valve 23 and opens the second valve 22 and the fourth valve 24 so that the refrigerant R flowing out from the first evaporator 11 and the second evaporator 12 is introduced only into the high-stage side compressor 4 without passing through the low-stage side compressor 3. Therefore, both the refrigerant R from the first evaporator 11 and the refrigerant R from the second evaporator 12 are compressed by the high-stage side compressor 4 without passing through the low-stage side compressor 3. [D mode]
    [0041] A D mode is when T1 ≒ T2 is satisfied and a temperature difference between the temperature of the refrigerant R flowing out from the condenser 5 and T1 and T2 is large. In this mode, as illustrated in Fig. 5, the control unit 30 closes the second valve 22 and the fourth valve 24 and opens the first valve 21 and the third valve 23 so that the refrigerant R flowing out from the first evaporator 11 and the second evaporator 12 is introduced into the low-stage side compressor 3. Therefore, both the refrigerant R from the first evaporator 11 and the refrigerant R from the second evaporator 12 are compressed by the low-stage side compressor 3, and thereafter, are compressed by the high-stage side compressor 4.
    [0042] The heat pump 1 according to the present embodiment described above includes the first evaporator 11 and the second evaporator 12. That is, the heat pump 1 has a multi-source type refrigerant circuit 2 including a plurality of heat exchangers having different heat exchange amounts or installation environments, that is, the first evaporator 11 and the second evaporator 12.
    [0043] Here, in each evaporator 10, the load (heat exchange amount) fluctuates and the temperature of the refrigerant R is changed. Accordingly, in some cases, the state of the refrigerant R directed toward the low-stage side compressor 3 and the high-stage side compressor 4 may not be optimum for compression in the low-stage side compressor 3 and the high-stage side compressor 4. In the present embodiment, the control unit 30 opens or closes the first flow path C1, the second flow path C2, the third flow path C3, and the fourth flow path C4 by the first valve 21, the second valve 22, the third valve 23, and the fourth valve 24 so that not only can the refrigerant R be introduced from the first evaporator 11 into the low-stage side compressor 3, but also the refrigerant R can be directly introduced into the high-stage side compressor 4 by bypassing the low-stage side compressor 3.
    [0044] Further, at the same time as switching of a circulation path of the refrigerant R from the first evaporator 11, a circulation path of the refrigerant R from the second evaporator 12 can be switched. That is, not only can the refrigerant R be introduced from the second evaporator 12 into the low-stage side compressor 3, but also the refrigerant R can be directly introduced into the high-stage side compressor 4 by bypassing the low-stage side compressor 3.
    [0045] Specifically, by operating the first valve 21, the second valve 22, the third valve 23, and the fourth valve 24 from the A mode to the D mode, according to the state of the refrigerant R flowing out from each evaporator 10 (11, 12), an introduction path of the refrigerant R can be switched to the compressor capable of performing optimum compression of the low-stage side compressor 3 and the high-stage side compressor 4. Therefore, the refrigerant R in a state optimum for compression can be introduced into the low-stage side compressor 3 and the high-stage side compressor 4, and an efficient operation can be performed.
    [0046] Further, by providing the control unit 30, the introduction path of the refrigerant R can be automatically switched to the compressor capable of performing optimum compression of the low-stage side compressor 3 and the high-stage side compressor 4 according to the state of the refrigerant R flowing out from each of the first evaporator 11 and the second evaporator 12.
    [0047] Further, since the flow of the refrigerant R can be switched between the A mode and the B mode, the refrigerant R from the first evaporator 11 can be introduced into any one of the low-stage side compressor 3 and the high-stage side compressor 4, and the refrigerant R from the second evaporator 12 can be introduced into any one of the low-stage side compressor 3 and the high-stage side compressor 4.
    [0048] That is, the flow of the refrigerant R from the first evaporator 11 and the flow of the refrigerant R from the second evaporator 12 do not interfere with each other, the refrigerant R circulates so that the flow of the refrigerant R from the first evaporator 11 and the flow of the refrigerant R from the second evaporator 12 cross each other, and can flow into the low-stage side compressor 3 and the high-stage side compressor 4. Therefore, a degree of freedom of an operation increases.
    [0049] Hereinbefore, the embodiment of the present invention is described in detail with reference to the drawings. However, respective configurations in the embodiment and a combination thereof are merely examples, and addition, omission, substitution, and other modifications of configurations can be made within a scope which does not depart from the gist of the present invention. In addition, the present invention is not limited by the embodiment, but is limited only by claims.
    [0050] For example, the control unit 30 does not necessarily have to be provided. In this case, the first valve 21, the second valve 22, the third valve 23, and the fourth valve 24 may be manually opened or closed.
    [0051] Further, three or more evaporators 10 may be provided, and the number of the evaporators 10 is not limited to the above-described case. [Industrial Applicability]
    [0052] According to the above-described heat pump, the refrigerant in the state optimum for compression can be introduced into the low-stage side compressor and the high-stage side compressor, and an efficient operation can be performed. [Reference Signs List]
    [0053] 1 Heat pump2 Refrigerant circuit3 Low-stage side compressor4 High-stage side compressor5 Condenser6 Expansion valve (expansion mechanism)10 Evaporator11 First evaporator12 Second evaporator15 Pipe21 First valve22 Second valve23 Third valve24 Fourth valve30 Control unitR RefrigerantR1, R2, R3 Heating mediumC1 First flow pathC2 Second flow pathC3 Third flow pathC4 Fourth flow path
    权利要求:
    Claims (3)
    [0001] A heat pump comprising:
    a low-stage side compressor;
    a high-stage side compressor which is connected to a downstream side of the low-stage side compressor in series,
    a condenser which is connected to a downstream side of the high-stage side compressor;
    an expansion mechanism which is connected to a downstream side of the condenser;
    a first evaporator and a second evaporator which are connected to a downstream side of the expansion mechanism in parallel;
    a first flow path through which a downstream side of the first evaporator and an upstream side of the low-stage side compressor are connected to each other;
    a first valve which opens or closes the first flow path;
    a second flow path through which the downstream side of the first evaporator and an upstream side of the high-stage side compressor are connected to each other;
    a second valve which opens or closes the second flow path;
    a third flow path through which a downstream side of the second evaporator and the upstream side of the low-stage side compressor are connected to each other;
    a third valve which opens or closes the third flow path;
    a fourth flow path through which the downstream side of the second evaporator and the upstream side of the high-stage side compressor are connected to each other; and
    a fourth valve which opens or closes the fourth flow path.
    [0002] The heat pump according to claim 1, further comprising:a control unit which controls opening or closing operations of the first valve, the second valve, the third valve, and the fourth valve based on loads on the first evaporator and the second evaporator.
    [0003] The heat pump according to claim 2,wherein the control unit controls the opening or closing operations of the first valve, the second valve, the third valve, and the fourth valve so that a first state where a refrigerant from the first evaporator is introduced into the low-stage side compressor and a refrigerant from the second evaporator is directly introduced into the high-stage side compressor and a second state where the refrigerant from the first evaporator is directly introduced into the high-stage side compressor and the refrigerant from the second evaporator is introduced into the low-stage side compressor are switchable to each other.
    类似技术:
    公开号 | 公开日 | 专利标题
    EP2557377B1|2021-06-02|Air conditioning and hot-water supply composite system
    EP1443287B1|2010-03-24|Multi-type air conditioner with plurality of distributor able to be shut off
    EP1659348B1|2016-04-13|Freezing apparatus
    US9316421B2|2016-04-19|Air-conditioning apparatus including unit for increasing heating capacity
    EP1437557B1|2011-12-21|Multi-type air conditioner with defrosting device
    US7523623B2|2009-04-28|Heat pump with reheat and economizer functions
    US6938438B2|2005-09-06|Vapor compression system with bypass/economizer circuits
    US8375741B2|2013-02-19|Refrigerant system with intercooler and liquid/vapor injection
    EP2833083B1|2016-11-02|Refrigeration device
    US7228707B2|2007-06-12|Hybrid tandem compressor system with multiple evaporators and economizer circuit
    US6701723B1|2004-03-09|Humidity control and efficiency enhancement in vapor compression system
    EP1980802B1|2019-09-04|Refrigeration system
    US10107533B2|2018-10-23|Air-conditioning apparatus with subcooling heat exchanger
    EP2975338B1|2020-11-25|Air conditioner
    EP2808621B1|2020-02-26|Air-conditioning device
    EP2230474B1|2016-10-26|Refrigeration device
    KR101127356B1|2012-03-29|Air conditioner
    KR100188860B1|1999-06-01|A refrigerator
    US9791193B2|2017-10-17|Air conditioner and method of controlling the same
    US20100199715A1|2010-08-12|Refrigerant system with bypass line and dedicated economized flow compression chamber
    KR100511287B1|2005-08-31|Air conditioner capable of defrosting and heating operation simultaneously and out door unit with self defrosting cycle for air conditioner
    EP1712854A2|2006-10-18|Wide temperature range heat pump
    EP2975335B1|2018-12-05|Air conditioner
    AU2007223486B2|2010-03-04|Refrigeration system
    US8316657B2|2012-11-27|Refrigerant system and control method
    同族专利:
    公开号 | 公开日
    JP2019086238A|2019-06-06|
    JP6373469B1|2018-08-15|
    CN111316047A|2020-06-19|
    WO2019093420A1|2019-05-16|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    法律状态:
    2019-05-18| STAA| Information on the status of an ep patent application or granted ep patent|Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE |
    2020-08-14| STAA| Information on the status of an ep patent application or granted ep patent|Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
    2020-08-14| PUAI| Public reference made under article 153(3) epc to a published international application that has entered the european phase|Free format text: ORIGINAL CODE: 0009012 |
    2020-09-16| 17P| Request for examination filed|Effective date: 20200602 |
    2020-09-16| AK| Designated contracting states|Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
    2020-09-16| AX| Request for extension of the european patent|Extension state: BA ME |
    2021-02-17| DAV| Request for validation of the european patent (deleted)|
    2021-02-17| DAX| Request for extension of the european patent (deleted)|
    2021-08-04| A4| Supplementary search report drawn up and despatched|Effective date: 20210706 |
    2021-08-04| RIC1| Information provided on ipc code assigned before grant|Ipc: F25B1/10 20060101AFI20210630BHEP Ipc: F25B5/02 20060101ALI20210630BHEP Ipc: F25B 41/22 20210101ALI20210630BHEP |
    优先权:
    申请号 | 申请日 | 专利标题
    [返回顶部]